Cerium's Production
Author:Rare Earth Supplier-Chinatungsten On…    Source:Chinatungsten Online    Update Time:2015-10-14 10:49:34

Cerium's Production


Chinatungsten Online News Net- Rare Earth News

 

The mineral mixtures are crushed, ground and treated with hot concentrated sulfuric acid to produce water-soluble sulfates of rare earths. The acidic filtrates are partially neutralized with sodium hydroxide to pH 3–4. Thorium precipitates out of solution as hydroxide and is removed. After that the solution is treated with ammonium oxalate to convert rare earths into their insoluble oxalates. The oxalates are converted to oxides by annealing. The oxides are dissolved in nitric acid that excludes one of the main components, cerium, whose salts are insoluble in HNO3. Metallic cerium is prepared by metallothermic reduction techniques, such as by reducing cerium fluoride or chloride with calcium, or by electrolysis of molten cerous chloride or other cerous halides. The metallothermic technique is used to produce high-purity cerium. The annual world production of cerium is in the region of 24,000 mt.

 

 

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